Potential of Nonfullerene Small Molecules with High Photovoltaic Performance

Over the past decades, fullerene derivatives have become the most successful electron acceptors in organic solar cells (OSCs) and have achieved great progress, with power conversion efficiencies (PCEs) of over 11 %. However, fullerenes have some drawbacks, such as weak absorption, limited energy‐level tunability, and morphological instability. In addition, fullerene‐based OSCs usually suffer from large energy losses of over 0.7 eV, which limits further improvements in the PCE. Recently, nonfullerene small molecules have emerged as promising electron acceptors in OSCs. Their highly tunable absorption spectra and molecular energy levels have enabled fine optimization of the resulting devices, and the highest PCE has surpassed 12 %. Furthermore, several studies have shown that OSCs based on small‐molecule acceptors (SMA) have very efficient charge generation and transport efficiency at relatively low energy losses of below 0.6 eV, which suggests great potential for the further improvement of OSCs. In this focus review, we analyze the challenges and potential of SMA‐based OSCs and discuss molecular design strategies for highly efficient SMAs.     

Analysis of survivorship life insurance portfolios with stochastic rates of return

A general portfolio of survivorship life insurance contracts is studied in a stochastic rate of return environment with a dependent mortality model. Two methods are used to derive the first two moments of the prospective loss random variable. The first one is based on the individual loss random variables while the second one studies annual stochastic cash flows. The distribution function of the present value of future losses at a given valuation time is derived. For illustrative purposes, an AR(1) process is used to model the stochastic rates of return, and the future lifetimes of a couple are assumed to follow a copula model. The effects of the mortality dependence, the portfolio size and the policy type, as well as the impact of investment strategies on the riskiness of portfolios of survivorship life insurance policies are analyzed by means of moments and probability distributions.     

Unit-linked life insurance policies: Optimal hedging in partially observable market models

In this paper we investigate the hedging problem of a unit-linked life insurance contract via the local risk-minimization approach, when the insurer has a restricted information on the market. In particular, we consider an endowment insurance contract, that is a combination of a term insurance policy and a pure endowment, whose final value depends on the trend of a stock market where the premia the policyholder pays are invested. To allow for mutual dependence between the financial and the insurance markets, we use the progressive enlargement of filtration approach. We assume that the stock price process dynamics depends on an exogenous unobservable stochastic factor that also influences the mortality rate of the policyholder. We characterize the optimal hedging strategy in terms of the integrand in the Galtchouk–Kunita–Watanabe decomposition of the insurance claim with respect to the minimal martingale measure and the available information flow. We provide an explicit formula by means of predictable projection of the corresponding hedging strategy under full information with respect to the natural filtration of the risky asset price and the minimal martingale measure. Finally, we discuss applications in a Markovian setting via filtering.     

Influences of Sr2+ Doping on Microstructure,Giant Dielectric Behavior,and Non-Ohmic Properties of CaCu3Ti4O12/CaTiO3 Ceramic Composites

The microstructure, dielectric response, and nonlinear current-voltage properties of Sr²⁺-doped CaCu₃Ti₄O₁₂/CaTiO₃ (CCTO/CTO) ceramic composites, which were prepared by a solid-state reaction method using a single step from the starting nominal composition of CCTO/CTO/xSrO, were investigated. The CCTO and CTO phases were detected in the X-ray diffraction patterns. The lattice parameter increased with increasing Sr²⁺ doping concentration. The phase compositions of CCTO and CTO were confirmed by energy-dispersive X-ray spectroscopy with elemental mapping in the sintered ceramics. It can be confirmed that most of the Sr²⁺ ions substituted into the CTO phase, while some minor portion substituted into the CCTO phase. Furthermore, small segregation of Cu-rich was observed along the grain boundaries. The dielectric permittivity of the CCTO/CTO composite slightly decreased by doping with Sr²⁺, while the loss tangent was greatly reduced. Furthermore, the dielectric properties in a high-temperature range of the Sr²⁺-doped CCTO/CTO ceramic composites can be improved. Interestingly, the nonlinear electrical properties of the Sr²⁺-doped CCTO/CTO ceramic composites were significantly enhanced. The improved dielectric and nonlinear electrical properties of the Sr²⁺-doped CCTO/CTO ceramic composites were explained by the enhancement of the electrical properties of the internal interfaces.     

Ultrasound Microbubbles Enhance the Efficacy of Insulin-Like Growth Factor-1 Therapy for the Treatment of Noise-Induced Hearing Loss

The application of insulin-like growth factor 1 (IGF-1) to the round window membrane (RWM) is an emerging treatment for inner ear diseases. RWM permeability is the key factor for efficient IGF-1 delivery. Ultrasound microbubbles (USMBs) can increase drug permeation through the RWM. In the present study, the enhancing effect of USMBs on the efficacy of IGF-1 application and the treatment effect of USMB-mediated IGF-1 delivery for noise-induced hearing loss (NIHL) were investigated. Forty-seven guinea pigs were assigned to three groups: the USM group, which received local application of recombinant human IGF-1 (rhIGF-1, 10 µg/µL) following application of USMBs to the RWM; the RWS group, which received IGF-1 application alone; and the saline-treated group. The perilymphatic concentration of rhIGF-1 in the USM group was 1.95- and 1.67- fold of that in the RWS group, 2 and 24 h after treatment, respectively. After 5 h of 118 dB SPL noise exposure, the USM group had the lowest threshold shift in auditory brainstem response, least loss of cochlear outer hair cells, and least reduction in the number of synaptic ribbons on postexposure day 28 among the three groups. The combination of USMB and IGF-1 led to a better therapeutic response to NIHL. Two hours after treatment, the USM group had significantly higher levels of Akt1 and Mapk3 gene expression than the other two groups. The most intense immunostaining for phosphor-AKT and phospho-ERK1/2 was detected in the cochlea in the USM group. These results suggested that USMB can be applied to enhance the efficacy of IGF-1 therapy in the treatment of inner ear diseases.     

A flexible block classical Gram–Schmidt skeleton with reorthogonalization

We investigate a variant of the reorthogonalized block classical Gram–Schmidt method for computing the QR factorization of a full column rank matrix. Our aim is to bound the loss of orthogonality even when the first local QR algorithm is only conditionally stable. In particular, this allows the use of modified Gram–Schmidt instead of Householder transformations as the first local QR algorithm. Numerical experiments confirm the stable behavior of the new variant. We also examine the use of non-QR local factorization and show by example that the resulting variants, although less stable, may also be applied to ill-conditioned problems.     

Effects of post-deposition annealing on chemical composition of SiNx film in SiO2/SiNx/SiO2/Si stacked structure

To systematically evaluate the quality of SiN_x films in multi-stacked structures, we investigated the effects of post-deposition annealing (PDA) on the film properties of SiN_x within the SiO₂/SiN_x/SiO₂/Si stacked structure by performing X-ray photoelectron spectroscopy (XPS), X-ray reflectivity (XRR), Fourier transform infrared (FT-IR) spectroscopy, and scanning transmission electron microscope–electron energy loss spectroscopy (STEM-EELS) analyses. The XPS results showed that PDA induces the oxidation of the SiN_x layer. In particular, new finding is that Si-rich SiN_x in the SiN_x layer is preferentially oxidized by PDA even in multi-stacked structure. The XRR results showed that the SiN_x layer becomes thinner, whereas the interface layer between the SiN_x layer and Si becomes thicker. It is concluded by STEM-EELS and XPS that this interface layer is SiON layer. The density of N–H and Si–H bonding within the stacked structure strongly depends on the PDA temperature. Our study helps elucidate the properties of SiN_x films in stacked structures from various perspectives.     

Optical constants of organic insulators in the UV range extracted from reflection electron energy loss spectra

Reflection electron energy loss spectroscopy (REELS) spectra were measured for seven insulating organic compounds (DNA, Irganox 1010, Kapton, polyethylene [PE], poly(methyl methacrylate) [PMMA], polystyrene [PS] and polytetrafluoroethylene [PTFE]). Optical constants and energy band gaps were extracted from the measured REELS spectra after elimination of multiple electron scattering via a deconvolution and fitting the normalised single scattering energy loss spectra to Drude and Drude–Lindhard model dielectric functions, constrained by the Kramers–Kronig sum and f-sum rules. Satisfactory agreement is found for those optical constants for which literature data exists. For PTFE, the observed features in the optical data correspond to its electronic structure.     

聚3-己基噻吩：非富勒烯太阳能电池中的量子效率损失和电压损失

聚3-己基噻吩(P3HT)以其合成工艺简单、成本低廉的优势,成为有机光伏领域中最具吸引力的电子给体材料之一。然而,目前P3HT: 非富勒烯太阳能电池的光伏性能仍然较差。在本工作中,我们证明了与P3HT: 富勒烯太阳能电池相比,较快的电荷转移态的非辐射衰减速率(K_nr)是导致P3HT: 非富勒烯太阳能电池中较低的量子效率和较高的电压损失的原因。然后,我们研究了基于非富勒烯受体ZY-4Cl的太阳能电池的工作机理。研究结果表明与P3HT: 非富勒烯体系相比,P3HT: ZY-4Cl中K_nr的降低改善了器件的量子效率,同时降低了电压损失。K_nr降低的原因可以部分归因于电荷转移态能量的增加。此外,给体分子和受体分子之间的距离(DA间距)的增大也是K_nr减少的重要原因。因此,我们得出结论：为了提高P3HT太阳能电池的性能,需进一步降低器件的K_nr,这可通过增加活性层中的DA间距来实现。     

金属橡胶材料阻尼测试的一个新方法

金属橡胶材料是一种新型减振缓冲材料。本文提出了一个金属橡胶材料阻尼性能的测试方法。基于粘弹性阻尼耗能的基本原理,在给定应变激励函数的条件下,构造了一个等效应力响应函数,由滞环面积相等建立了一组包含实测应力响应和等效应力响应的等效耗能方程,将应变激励函数离散得到了损耗因子的计算表达式,由此可以通过实测应力方便地计算出损耗因子。该方法不仅便于对大阻尼材料的阻尼进行测试,而且具有精度高的优点。依据这一方法对金属橡胶材料进行了测试,测试结果表明我们开发的金属橡胶材料有很好的阻尼减振性能。